|









| |
|
RARE EARTH ELEMENTS
|
|
 |
|
Cerium, symbol Ce, soft, gray metallic element that is
the most abundant of the
rare earth elements.
Cerium is in the
lanthanide series
of the periodic table. Its atomic number
is 58.
Cerium was discovered in 1803 by the Swedish chemists Baron
Jöns Jakob Berzelius and Wilhelm Hisinger, and in the same year,
independently, by the German chemist Martin Heinrich Klaproth; the pure
metallic element was not isolated until 1875.
Cerium ranks 26th in natural abundance among the elements in
the earth's crust. It occurs with other rare earth metals in monazite, which
is found widely distributed worldwide, and bastnasite, found in southern
California. It also occurs in the minerals cerite, found in Sweden, and
allanite, found in Greenland and New York state. Cerium is the only one of
the rare earth metals that can be easily separated from the others. Cerium
melts at 798° C (1468° F), boils at about 3443° C (about 6229° F), and has a
specific gravity of 6.77; the element has an atomic weight of 140.12.

|
|
 |
|
Dysprosium, symbol Dy, metallic element with an atomic
number of 66. Dysprosium is one of the
rare earth elements
in the
lanthanide series
of the periodic table. The element was
discovered in 1886 by Paul Émile Lecoq de Boisbaudran, who separated one of
its compounds from an oxide of
holmium.
Dysprosium is 42nd in abundance among the elements in the
earth's crust. The compounds of dysprosium are found in gadolinite, xenotime,
euxenite, and fergusonite in Norway, the United States, Brazil, India, and
Australia. Its salts are either yellow or yellow-green in color, the most
common being a chloride (DyCl 3),
a nitrate (Dy(NO3)3·5H2O),
and a sulfate (Dy 2(SO4)3·8H2O).
The salts of dysprosium have an extremely high magnetic susceptibility.
Dysprosium usually occurs as the white oxide dysprosia (Dy2O3),
with erbium
and holmium, two other rare earth elements.
Dysprosium melts at about 1412°
C (about 2574° F), boils at about 2567° C (about 4653° F), and has a
specific gravity of 8.55. The atomic weight of dysprosium is 162.50.

|
|
 |
|
Erbium, symbol Er, metallic element, whose atomic number
is 68. The Swedish chemist Carl Gustav Mosander discovered erbium in 1843.
Erbium occurs mostly in the same minerals and in the same areas as
dysprosium. One of the rare earth elements, erbium is 43rd in abundance
among the elements of the earth's crust. The atomic weight of erbium is
167.26. The element melts at about 1529° C (about 2784° F), boils at about
2868° C (about 5194° F), and has a specific gravity of 9.1.
Metallic erbium has a bright silvery luster. Erbium oxide,
Er 2O
3, is a rose-red compound slowly soluble
in many mineral acids, forming a series of rose-colored salts, solutions of
which have a sweet, astringent taste.

|
|
 |
|
Europium, symbol Eu, soft, silvery metallic element that
is among the least abundant of the
rare earth elements.
Europium is in the
lanthanide series
of the periodic table; its atomic number
is 63.
Europium was discovered spectroscopically by the French
chemist Eugène Demarçay in 1896. It ranks 50th in order of abundance of the
elements in the earth's crust; it occurs in monazite, bastnaesite, and other
rare earth minerals, as well as in fission products of uranium, thorium, and
plutonium. Europium melts at 822° C (1512° F) boils at about 1527° C (about
2781° F), and has a specific gravity of 5.2. The atomic weight of europium
is 151.96.

|
|
 |
|
Gadolinium, symbol Gd, silvery white metallic element
with an atomic number of 64. Gadolinium is one of the
rare earth elements
in the
lanthanide series
of the periodic table. It is named after
the Finnish chemist John Gadolin.
Gadolinium occurs with other rare earth elements in many
minerals, such as samarskite, gadolinite, monazite, and some varieties of
Norwegian ytterspar. It is the 41st element in order of abundance in the
crust of the earth. Gadolinium melts at about 1313° C (about 2395° F), boils
at about 3273° C (about 5923° F), and has a specific gravity of 7.9. The
atomic weight of the element is 157.25.
Gadolinium oxide was first separated from other rare earth
elements by the Swiss chemist Jean de Marignac in 1880. The oxide and many
salts of gadolinium have been prepared. Gadolinium oxide is white and the
salts are colorless.

|
|
 |
|
Holmium, symbol Ho, silver-colored metallic element with
an atomic number of 67. Holmium is one of the most paramagnetic substances
known.
Holmium was discovered in 1878 by the Swiss chemists Jacques
Louis Soret and Marc Delafontaine, and, independently, by the Swedish
chemist Per Teodor Cleve in 1879. Cleve named the element after his native
city of Stockholm, Sweden (the latinized name of Stockholm is Holmia).
Holmium is one of the least abundant of the rare earth
metals, ranking 55th in order of abundance of the elements in the earth's
crust. Holmium has an atomic weight of 164.93. It melts at about 1474° C
(about 2685° F), boils at about 2700° C (about 4892° F), and has a specific
gravity of 8.8. Holmium occurs in gadolinite and other minerals containing
rare earths. Holmium oxide, Ho 2O3,
a grayish-white powder, and a few salts, such as the sulfate, have been
prepared.

|
|
 |
|
Lanthanum (Greek lanthanein, "to escape notice"),
symbol La, metallic element with an atomic number of 57. Lanthanum is one of
the
rare earth elements
of the periodic table. Lanthanum is
often regarded as the first member of the
lanthanide series,
to which it gives its name.
Lanthanum was discovered by the Swedish chemist Carl Gustav
Mosander in 1839. It burns in air at about 450° C (about 842° F) to form
lanthanum oxide, La 2
O3. It
forms colorless trivalent salts, including one of the strongest trivalent
bases, which is used by analytical chemists. It generally occurs with other
rare earth elements in such minerals as apatite and monazite and in certain
kinds of calcite and fluorspar. It is fairly common, ranking 28th in order
of abundance of the elements in the earth's crust.
Lanthanum melts at about 918° C (about 1684° F), boils at
about 3464° C (about 6267° F), and has a specific gravity of 6.15. The
atomic weight of lanthanum is 138.91.

|
|
 |
|
Lutetium, symbol Lu, silvery white metallic element with
an atomic number of 71. Lutetium is one of the
rare earth elements
of the periodic table.
Lutetium was discovered independently by two investigators,
the French chemist Georges Urbain in 1907 and the Austrian chemist Carl Auer
von Welsbach about the same time. It was named by Urbain, who derived the
word from Lutetia, the ancient name of Paris. Lutetium occurs in
various rare earth minerals, usually associated with
yttrium.
It is the rarest of the rare earth elements and ranks 59th in order of
abundance of the elements in the earth's crust. Several trivalent salts are
known. A natural radioactive isotope of lutetium that has a half-life of
about 30 billion years is used in determining the age of meteorites in
relation to the age of the earth.
Lutetium melts at about 1663° C (about 3025° F), boils at
about 3402° C (about 6156° F) and has a specific gravity of 9.84. The atomic
weight of lutetium is 174.97.

|
|
 |
|
Neodymium, symbol Nd, silvery metallic element with an
atomic number of 60. Neodymium is one of the
rare earth elements
in the
lanthanide series
of the periodic table. Neodymium was
isolated in 1885 by the Austrian chemist Baron Carl Auer von Welsbach, who
separated it from
praseodymium. Neodymium
and praseodymium had previously been regarded as a single element, called
didymium. Neodymium ranks 27th in order of abundance of the elements in the
earth's crust. It forms trivalent salts, which are rose-red or
reddish-violet in color.
Neodymium melts at about 1021° C (about 1870° F), boils at
about 3074° C (about 5565° F), and has a specific gravity of 7.01. The
atomic weight of neodymium is 144.24.

|
|
 |
|
Praseodymium, symbol Pr, silvery metallic element with
an atomic number of 59. Praseodymium is one of the
rare earth elements
in the
lanthanide series
of the periodic table.
Praseodymium was discovered in 1885 by the German chemist
Carl Auer von Welsbach, who separated it from
neodymium.
A mixture of the two elements had formerly been considered a single element,
called didymium. Praseodymium is a paramagnetic metal that corrodes
rapidly in moist air. It forms green trivalent salts.
Praseodymium is widely distributed in nature and ranks 37th
in order of abundance of the elements in the crust of the earth. It is found
in cerite and other rare earth minerals.
Praseodymium melts at about 931° C (1708° F), boils at about
3520° C (about 6368° F), and has a specific gravity of 6.64. The atomic
weight of praseodymium is 140.9.

|
|
 |
|
Samarium, symbol Sm, hard, brittle, lustrous metallic
element. Samarium is one of the
rare earth elements
in the lanthanide
series of the
periodic table. The atomic number of
samarium is 62.
Samarium was discovered in 1879 by the French chemist P. E.
Lecoq de Boisbaudran. The metal ignites in air at about 150° C (about 302°
F). Like other rare earth metals, it is found in minerals such as cerite,
gadolinite, and samarskite. It is 40th in order of abundance of the elements
in the earth's crust. Samarium forms chiefly trivalent compounds; the salts
are pale yellow in color.
Samarium melts at about 1074° C (about 1965° F), boils at
about 1794° C (about 3261° F), and has a specific gravity of 7.52. The
atomic weight of samarium is 150.4.

|
|
 |
|
Terbium, symbol Tb, metallic element with an atomic
number of 65. Terbium is one of the
rare earth elements
in the
lanthanide series
of the periodic table.
Terbium was discovered in 1843 by the Swedish chemist Carl
Gustav Mosander. It ranks about 58th in natural abundance among the elements
in crustal rock. It occurs in minute quantities as a white oxide known as
terbia, Tb 2O3,
in such minerals as gadolinite.
Terbium melts at about 1356° C (about 2473° F), boils at
about 3230° C (about 5846° F), and has a specific gravity of 8.23. The
atomic weight of terbium is 158.925.

|
|
 |
|
Thulium, symbol Tm, silver-gray metallic element that is
the rarest of the
rare earth elements.
Thulium is in the
lanthanide series
of the periodic table; the atomic number
of thulium is 69.
Thulium was discovered in 1879 by the Swedish chemist Per
Teodor Cleve. Thulium ranks 61st in abundance among the elements in the
crust of the earth and is found in small quantities in such rare earth
minerals as euxenite, gadolinite, and blomstrandine. The metal can be
isolated by reduction of its oxide, Tm 2O3,
and is soft, malleable, and ductile.
Thulium melts at about 1545° C (about 2813° F), boils at
about 1950° C (about 3542° F), and has a specific gravity of 9.34. The
atomic weight of thulium is 168.934.

|
|
 |
|
Ytterbium, symbol Yb, soft, malleable, ductile metallic
element that has a bright, silvery luster. Ytterbium is one of the
rare earth elements
in the
lanthanide series
of the periodic table. The atomic number
of ytterbium is 70.
In 1878, the Swiss chemist Jean Charles de Marignac
separated a new substance from the rare earth elements and named it
ytterbium. In 1907 and 1908, however, the French chemist Georges Urbain and
the Austrian chemist Carl Auer von Welsbach independently separated
Marignac's ytterbium into two elements, which are now called
ytterbium and
lutetium.
Ytterbium is reasonably stable but reacts slowly with water
to liberate hydrogen. Ytterbium occurs in combination with such minerals as
xenotime, euxenite, monazite, and gadolinite. It ranks about 44th in natural
abundance among the elements in the earth's crust.
Ytterbium melts at 819° C (about 1506° F), boils at about
1196° C (about 2185° F), and has a specific gravity of 7. The atomic weight
of ytterbium is 173.04.

|
|
 |
|
Yttrium, symbol Y, silver-white metallic element with an
atomic number of 39. Yttrium is one of the transition elements of the
periodic table.
Yttrium was isolated by the Swedish chemist Carl Gustav
Mosander in 1843. Yttrium metal can be prepared by the reduction of yttrium
triflouride (YF 3)
with calcium. It oxidizes readily in air to the oxide Y2O3
and dissolves in hot water to form the hydroxide Y(OH)3.
Yttrium ranks about 29th in abundance of the elements in the earth's crust.
Yttrium is found as an oxide in most of the rare earth minerals.
Yttrium melts at about 1522° C (about 2772° F), boils at
about 3338° C (about 6040° F), and has a specific gravity of 4.47. The
atomic weight of yttrium is 88.906. Yttrium is sometimes included among the
rare earth elements.

|
|