Rare Earth Zirconium Refractory Titanium

 

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RARE EARTH ELEMENTS

               
 
   
                   

Cerium, symbol Ce, soft, gray metallic element that is the most abundant of the rare earth elements. Cerium is in the lanthanide series of the periodic table. Its atomic number is 58.

Cerium was discovered in 1803 by the Swedish chemists Baron Jöns Jakob Berzelius and Wilhelm Hisinger, and in the same year, independently, by the German chemist Martin Heinrich Klaproth; the pure metallic element was not isolated until 1875.

Cerium ranks 26th in natural abundance among the elements in the earth's crust. It occurs with other rare earth metals in monazite, which is found widely distributed worldwide, and bastnasite, found in southern California. It also occurs in the minerals cerite, found in Sweden, and allanite, found in Greenland and New York state. Cerium is the only one of the rare earth metals that can be easily separated from the others. Cerium melts at 798° C (1468° F), boils at about 3443° C (about 6229° F), and has a specific gravity of 6.77; the element has an atomic weight of 140.12.


Dysprosium, symbol Dy, metallic element with an atomic number of 66. Dysprosium is one of the rare earth elements in the lanthanide series of the periodic table. The element was discovered in 1886 by Paul Émile Lecoq de Boisbaudran, who separated one of its compounds from an oxide of holmium.

Dysprosium is 42nd in abundance among the elements in the earth's crust. The compounds of dysprosium are found in gadolinite, xenotime, euxenite, and fergusonite in Norway, the United States, Brazil, India, and Australia. Its salts are either yellow or yellow-green in color, the most common being a chloride (DyCl3), a nitrate (Dy(NO3)3·5H2O), and a sulfate (Dy 2(SO4)3·8H2O). The salts of dysprosium have an extremely high magnetic susceptibility. Dysprosium usually occurs as the white oxide dysprosia (Dy2O3), with erbium and holmium, two other rare earth elements.

Dysprosium melts at about 1412° C (about 2574° F), boils at about 2567° C (about 4653° F), and has a specific gravity of 8.55. The atomic weight of dysprosium is 162.50.


Erbium, symbol Er, metallic element, whose atomic number is 68. The Swedish chemist Carl Gustav Mosander discovered erbium in 1843. Erbium occurs mostly in the same minerals and in the same areas as dysprosium. One of the rare earth elements, erbium is 43rd in abundance among the elements of the earth's crust. The atomic weight of erbium is 167.26. The element melts at about 1529° C (about 2784° F), boils at about 2868° C (about 5194° F), and has a specific gravity of 9.1.

Metallic erbium has a bright silvery luster. Erbium oxide, Er2O 3, is a rose-red compound slowly soluble in many mineral acids, forming a series of rose-colored salts, solutions of which have a sweet, astringent taste.


Europium, symbol Eu, soft, silvery metallic element that is among the least abundant of the rare earth elements. Europium is in the lanthanide series of the periodic table; its atomic number is 63.

Europium was discovered spectroscopically by the French chemist Eugène Demarçay in 1896. It ranks 50th in order of abundance of the elements in the earth's crust; it occurs in monazite, bastnaesite, and other rare earth minerals, as well as in fission products of uranium, thorium, and plutonium. Europium melts at 822° C (1512° F) boils at about 1527° C (about 2781° F), and has a specific gravity of 5.2. The atomic weight of europium is 151.96.


Gadolinium, symbol Gd, silvery white metallic element with an atomic number of 64. Gadolinium is one of the rare earth elements in the lanthanide series of the periodic table. It is named after the Finnish chemist John Gadolin.

Gadolinium occurs with other rare earth elements in many minerals, such as samarskite, gadolinite, monazite, and some varieties of Norwegian ytterspar. It is the 41st element in order of abundance in the crust of the earth. Gadolinium melts at about 1313° C (about 2395° F), boils at about 3273° C (about 5923° F), and has a specific gravity of 7.9. The atomic weight of the element is 157.25.

Gadolinium oxide was first separated from other rare earth elements by the Swiss chemist Jean de Marignac in 1880. The oxide and many salts of gadolinium have been prepared. Gadolinium oxide is white and the salts are colorless.


Holmium, symbol Ho, silver-colored metallic element with an atomic number of 67. Holmium is one of the most paramagnetic substances known.

Holmium was discovered in 1878 by the Swiss chemists Jacques Louis Soret and Marc Delafontaine, and, independently, by the Swedish chemist Per Teodor Cleve in 1879. Cleve named the element after his native city of Stockholm, Sweden (the latinized name of Stockholm is Holmia).

Holmium is one of the least abundant of the rare earth metals, ranking 55th in order of abundance of the elements in the earth's crust. Holmium has an atomic weight of 164.93. It melts at about 1474° C (about 2685° F), boils at about 2700° C (about 4892° F), and has a specific gravity of 8.8. Holmium occurs in gadolinite and other minerals containing rare earths. Holmium oxide, Ho2O3, a grayish-white powder, and a few salts, such as the sulfate, have been prepared.


Lanthanum (Greek lanthanein, "to escape notice"), symbol La, metallic element with an atomic number of 57. Lanthanum is one of the rare earth elements of the periodic table. Lanthanum is often regarded as the first member of the lanthanide series, to which it gives its name.

Lanthanum was discovered by the Swedish chemist Carl Gustav Mosander in 1839. It burns in air at about 450° C (about 842° F) to form lanthanum oxide, La2 O3. It forms colorless trivalent salts, including one of the strongest trivalent bases, which is used by analytical chemists. It generally occurs with other rare earth elements in such minerals as apatite and monazite and in certain kinds of calcite and fluorspar. It is fairly common, ranking 28th in order of abundance of the elements in the earth's crust.

Lanthanum melts at about 918° C (about 1684° F), boils at about 3464° C (about 6267° F), and has a specific gravity of 6.15. The atomic weight of lanthanum is 138.91.


Lutetium, symbol Lu, silvery white metallic element with an atomic number of 71. Lutetium is one of the rare earth elements of the periodic table.

Lutetium was discovered independently by two investigators, the French chemist Georges Urbain in 1907 and the Austrian chemist Carl Auer von Welsbach about the same time. It was named by Urbain, who derived the word from Lutetia, the ancient name of Paris. Lutetium occurs in various rare earth minerals, usually associated with yttrium. It is the rarest of the rare earth elements and ranks 59th in order of abundance of the elements in the earth's crust. Several trivalent salts are known. A natural radioactive isotope of lutetium that has a half-life of about 30 billion years is used in determining the age of meteorites in relation to the age of the earth.

Lutetium melts at about 1663° C (about 3025° F), boils at about 3402° C (about 6156° F) and has a specific gravity of 9.84. The atomic weight of lutetium is 174.97.


Neodymium, symbol Nd, silvery metallic element with an atomic number of 60. Neodymium is one of the rare earth elements in the lanthanide series of the periodic table. Neodymium was isolated in 1885 by the Austrian chemist Baron Carl Auer von Welsbach, who separated it from praseodymium. Neodymium and praseodymium had previously been regarded as a single element, called didymium. Neodymium ranks 27th in order of abundance of the elements in the earth's crust. It forms trivalent salts, which are rose-red or reddish-violet in color.

Neodymium melts at about 1021° C (about 1870° F), boils at about 3074° C (about 5565° F), and has a specific gravity of 7.01. The atomic weight of neodymium is 144.24.


Praseodymium, symbol Pr, silvery metallic element with an atomic number of 59. Praseodymium is one of the rare earth elements in the lanthanide series of the periodic table.

Praseodymium was discovered in 1885 by the German chemist Carl Auer von Welsbach, who separated it from neodymium. A mixture of the two elements had formerly been considered a single element, called didymium. Praseodymium is a paramagnetic metal that corrodes rapidly in moist air. It forms green trivalent salts.

Praseodymium is widely distributed in nature and ranks 37th in order of abundance of the elements in the crust of the earth. It is found in cerite and other rare earth minerals.

Praseodymium melts at about 931° C (1708° F), boils at about 3520° C (about 6368° F), and has a specific gravity of 6.64. The atomic weight of praseodymium is 140.9.


Samarium, symbol Sm, hard, brittle, lustrous metallic element. Samarium is one of the rare earth elements in the lanthanide series of the periodic table. The atomic number of samarium is 62.

Samarium was discovered in 1879 by the French chemist P. E. Lecoq de Boisbaudran. The metal ignites in air at about 150° C (about 302° F). Like other rare earth metals, it is found in minerals such as cerite, gadolinite, and samarskite. It is 40th in order of abundance of the elements in the earth's crust. Samarium forms chiefly trivalent compounds; the salts are pale yellow in color.

Samarium melts at about 1074° C (about 1965° F), boils at about 1794° C (about 3261° F), and has a specific gravity of 7.52. The atomic weight of samarium is 150.4.


Terbium, symbol Tb, metallic element with an atomic number of 65. Terbium is one of the rare earth elements in the lanthanide series of the periodic table.

Terbium was discovered in 1843 by the Swedish chemist Carl Gustav Mosander. It ranks about 58th in natural abundance among the elements in crustal rock. It occurs in minute quantities as a white oxide known as terbia, Tb2O3, in such minerals as gadolinite.

Terbium melts at about 1356° C (about 2473° F), boils at about 3230° C (about 5846° F), and has a specific gravity of 8.23. The atomic weight of terbium is 158.925.


Thulium, symbol Tm, silver-gray metallic element that is the rarest of the rare earth elements. Thulium is in the lanthanide series of the periodic table; the atomic number of thulium is 69.

Thulium was discovered in 1879 by the Swedish chemist Per Teodor Cleve. Thulium ranks 61st in abundance among the elements in the crust of the earth and is found in small quantities in such rare earth minerals as euxenite, gadolinite, and blomstrandine. The metal can be isolated by reduction of its oxide, Tm2O3, and is soft, malleable, and ductile.

Thulium melts at about 1545° C (about 2813° F), boils at about 1950° C (about 3542° F), and has a specific gravity of 9.34. The atomic weight of thulium is 168.934.


Ytterbium, symbol Yb, soft, malleable, ductile metallic element that has a bright, silvery luster. Ytterbium is one of the rare earth elements in the lanthanide series of the periodic table. The atomic number of ytterbium is 70.

In 1878, the Swiss chemist Jean Charles de Marignac separated a new substance from the rare earth elements and named it ytterbium. In 1907 and 1908, however, the French chemist Georges Urbain and the Austrian chemist Carl Auer von Welsbach independently separated Marignac's ytterbium into two elements, which are now called ytterbium and lutetium.

Ytterbium is reasonably stable but reacts slowly with water to liberate hydrogen. Ytterbium occurs in combination with such minerals as xenotime, euxenite, monazite, and gadolinite. It ranks about 44th in natural abundance among the elements in the earth's crust.

Ytterbium melts at 819° C (about 1506° F), boils at about 1196° C (about 2185° F), and has a specific gravity of 7. The atomic weight of ytterbium is 173.04.


Yttrium, symbol Y, silver-white metallic element with an atomic number of 39. Yttrium is one of the transition elements of the periodic table.

Yttrium was isolated by the Swedish chemist Carl Gustav Mosander in 1843. Yttrium metal can be prepared by the reduction of yttrium triflouride (YF3) with calcium. It oxidizes readily in air to the oxide Y2O3 and dissolves in hot water to form the hydroxide Y(OH)3. Yttrium ranks about 29th in abundance of the elements in the earth's crust. Yttrium is found as an oxide in most of the rare earth minerals.

Yttrium melts at about 1522° C (about 2772° F), boils at about 3338° C (about 6040° F), and has a specific gravity of 4.47. The atomic weight of yttrium is 88.906. Yttrium is sometimes included among the rare earth elements.


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